If cooling doesn't work or it really was thoroughly cooled the first time, do the exact opposite and heat things up. Pop it back in the oven for a few minutes — not long enough to overbake it, but long enough to create a temperature shift. If the pan was greased or the cake was made with butter, this can loosen it up enough to release the cake.
If you're afraid of overbaking, you can lightly steam it. King Arthur Flour recommends putting a rolled kitchen towel in the sink to create a little nest, pouring boiling water into the sink, and nestling the cake pan into the towel. Tightly cover the cake with foil to help trap steam and avoid a damp, splashed cake. Lay another towel over the top of the sink to trap the steam. After about 15 minutes, try to turn it out again. This tip is specifically for stuck bundt cakes, but should work for all cake pans.
Though it may be tempting to shove some utensils like forks under the cake and pry it out, this can make matters much worse in the future. Many cake pans are designed to be nonstick (whether you believe that or not while your cake is stuck), but scratching the surface will create even more sticking in the future. If you're going to try to pry, use a thin, flexible, silicone or rubber spatula and very carefully apply leverage around the cake.
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